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The three main contributions to extinction by the Earth's atmosphere of relevance to ground-based astronomy are Rayleigh scattering by air molecules, molecular absorption and aerosol scattering. The method outlined in Hayes and Latham (1975) gives the mean extinction for an aerosol-free atmosphere, as follows:
 in
 in  m) and 
altitude (h in km) dependence of Rayleigh vertical extinction is approximated 
by:
m) and 
altitude (h in km) dependence of Rayleigh vertical extinction is approximated 
by:
 where the scale height of the lower troposphere is taken to be 7.996 km and
h = 2.369 km for the Roque de los Muchachos Observatory.
where the scale height of the lower troposphere is taken to be 7.996 km and
h = 2.369 km for the Roque de los Muchachos Observatory.
The index of refraction term is given by:
 
Vertical extinction by ozone is approximated by:
 
where  (cm
 (cm ) is the absorption coefficient (Gast 1960) and
) is the absorption coefficient (Gast 1960) and  (atm cm) is the total ozone above the observatory.
 
(atm cm) is the total ozone above the observatory.  is independent
of the observatory altitude, since atmospheric
 is independent
of the observatory altitude, since atmospheric  is concentrated
between 10 and 35 km. It does, however, exhibit seasonal variations and
it can also vary significantly on time scales as short as a few hours. The
extinction curve here uses a mean annual value of
 is concentrated
between 10 and 35 km. It does, however, exhibit seasonal variations and
it can also vary significantly on time scales as short as a few hours. The
extinction curve here uses a mean annual value of  appropriate
to the latitude of La Palma, taken from Allen (1963).
 appropriate
to the latitude of La Palma, taken from Allen (1963).
The total vertical extinction coefficient  for an aerosol-free
atmosphere is then given by;
 for an aerosol-free
atmosphere is then given by;
 
Values of  have been calculated every 10Å  between 3000 and
3500Å  and every 50Å  between 3500 and 11000Å  and are collected in
Table 1. The extinction curve is shown in Figure 1, together with preliminiary
measurements obtained on dust-free nights (Andrews 1985, private
communication).
 have been calculated every 10Å  between 3000 and
3500Å  and every 50Å  between 3500 and 11000Å  and are collected in
Table 1. The extinction curve is shown in Figure 1, together with preliminiary
measurements obtained on dust-free nights (Andrews 1985, private
communication).
 
  
  
  
 