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The three main contributions to extinction by the Earth's atmosphere of relevance to ground-based astronomy are Rayleigh scattering by air molecules, molecular absorption and aerosol scattering. The method outlined in Hayes and Latham (1975) gives the mean extinction for an aerosol-free atmosphere, as follows:
The index of refraction term is given by:
Vertical extinction by ozone is approximated by:
where (cm) is the absorption coefficient (Gast 1960) and (atm cm) is the total ozone above the observatory. is independent of the observatory altitude, since atmospheric is concentrated between 10 and 35 km. It does, however, exhibit seasonal variations and it can also vary significantly on time scales as short as a few hours. The extinction curve here uses a mean annual value of appropriate to the latitude of La Palma, taken from Allen (1963).
The total vertical extinction coefficient for an aerosol-free atmosphere is then given by;
Values of have been calculated every 10Å between 3000 and 3500Å and every 50Å between 3500 and 11000Å and are collected in Table 1. The extinction curve is shown in Figure 1, together with preliminiary measurements obtained on dust-free nights (Andrews 1985, private communication).